Journal of Chemical Physics
Chemistry | Physical Chemistry
The preparation of Hx TaS2 (0 < x < 0.87) is described. The compounds are only marginally stable at room temperature, slowly evolving H2S and H2 (and possibly Hp in air). Magnetic susceptibility data show that a low temperature transformation in 2H ... TaS2 (at so•K) is suppressed with the addition of hydrogen, and· at the same time the superconducting transition temperature T c rises from 0.8 to ~4.2•K at x = 0.11. Heat capacity measurements near this concentration show the superconductivity to be a bulk effect. Finally, by correlation of this data with susceptibility and T c measurements in other intercalation compounds, we suggest that the rise of T c (at low electron transfer) is due to suppression of the low temperature transformation and not due to an excitonic mechanism of superconductivity.
D. W. Murphy, F. J. DiSalvo, G. W. Hull, J. V. Waszczak, S. F. Meyers, G. R. Stewart, S. Early, Juana Vivó Acrivos, and T. H. Geballe. "Properties of HxTaS2" Journal of Chemical Physics (1975): 967-972. https://doi.org/10.1063/1.430512