Document Type
Article
Publication Date
January 2015
Publication Title
Inorganic Chemistry
Volume
54
Issue Number
1
First Page
143
Last Page
152
DOI
10.1021/ic5019136
Disciplines
Chemistry | Inorganic Chemistry
Abstract
A series of chiral cyclometalated platinum(II) complexes, [Pt((−)-L1)(Dmpi)]Cl ((−)-1), [Pt((+)-L1)(Dmpi)]Cl ((+)-1), [Pt((−)-L2)(Dmpi)]Cl ((−)-2), [Pt((+)-L2)(Dmpi)]Cl ((+)-2), [Pt3((−)-L2)2(Dmpi)4](ClO4)4 ((−)-3), and [Pt3((+)-L2)2(Dmpi)4](ClO4)4 ((+)-3) [(−)-L1 = (−)-4,5-pinene-6′-phenyl-2,2′-bipyridine, (+)-L1 = (+)-4,5-pinene-6′-phenyl-2,2′-bipyridine), (−)-L2 = (−)-1,3-bis(2-(4,5-pinene)pyridyl)benzene, (+)-L2 = (+)-1,3-bis(2-(4,5-pinene)pyridyl)benzene, Dmpi = 2,6-dimethylphenyl isocyanide], have been designed and synthesized. In aqueous solutions, (−)-1 and (+)-1 aggregate into one-dimensional helical chain structures through Pt···Pt, π–π, and hydrophobic–hydrophobic interactions. (−)-3 and (+)-3 represent a novel helical structure with Pt–Pt bonds. The formation of helical structures results in enhanced and distinct chiroptical properties as evidenced by circular dichroism spectra. Circularly polarized luminescence (CPL) was observed from the aggregates of (−)-1 and (+)-1 in water, as well as (−)-3 and (+)-3 in dichloromethane. The CPL activity can be switched reversibly (for (−)-1 and (+)-1) or irreversibly (for (−)-3 and (+)-3) by varying the temperature.
Recommended Citation
Xiao-Peng Zhang Zhang, Victoria Chang, Jian Liu, Xiao-Liang Yang, Wei Huan, Yizhi Li, Cheng-Hui Li, Gilles Muller, and Xiao-Zeng You. "Potential Switchable Circularly Polarized Luminescence from Chiral Cyclometalated Platinum(II) Complexes" Inorganic Chemistry (2015): 143-152. https://doi.org/10.1021/ic5019136
Comments
This article was originally published in Inorganic Chemistry, volume 54, issue 1, 2015. It can also be found online at this link.
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