Surface functionality and formation mechanisms of carbon and graphene quantum dots

Publication Date

12-1-2020

Document Type

Article

Publication Title

Diamond and Related Materials

Volume

110

DOI

10.1016/j.diamond.2020.108101

Abstract

Graphene quantum dots (GQDs) and Carbon dots (C-dots) have been widely studied in recent years due to their structural and optoelectrical properties. These properties have prompted the exploration of the role of these carbon-based materials in many potential applications. This includes solar cells, photodetectors, bioimaging, sensors, batteries and drug delivery. These properties and applications of GQDs and C-dots are highly dependent on their size, shape and surface functionality. In this work, GQDs and C-dots mixtures have been synthesized by an inexpensive wet chemical method by varying the synthesis temperature from 85°, 100° to 115 °C. The surface functionalities of the synthesized carbon-based materials were investigated by several analytical methods. We discovered a higher degree of oxidation at higher temperatures. The mechanism of formation of different sized GQDs and C-dots with different functionalities have been explained with the help of XPS and NEXAFS analysis. The influence of size and surface functionalities on the optical properties of these nanomaterials is analyzed by UV–Vis and PL spectroscopic techniques. This study demonstrates that physicochemical properties of GQDs and C-dots can be controlled by changing the synthesis temperature.

Funding Sponsor

San José State University

Keywords

Formation mechanism, Graphene quantum dots, Near edge X-ray absorption fine structure, X-ray photo-electron spectroscopy

Department

Chemical and Materials Engineering; Chemistry; Biomedical Engineering

Link to Full Text

Share

COinS