Valence tautomerism in a cobalt-verdazyl coordination compound
Publication Date
4-25-2020
Document Type
Article
Publication Title
Chemical Communications
Volume
56
Issue
32
DOI
10.1039/d0cc01770a
First Page
4400
Last Page
4403
Abstract
Coordination of 1-isopropyl-3,5-dipyridyl-6-oxoverdazyl to cobalt results in a dication best described in the solid state as a high spin cobalt(ii) ion coordinated to two radical ligands with an S = 3/2 ground state. On dissolution in acetonitrile, the cobalt(ii) form equilibrates with a cobalt(iii) valence tautomer with an S = 1/2 ground state.
Funding Number
1058077
Funding Sponsor
National Science Foundation
Department
Chemistry
Recommended Citation
Connor Fleming, Dorothy Chung, Servando Ponce, David J.R. Brook, Jeffrey Daros, Raja Das, Andrew Ozarowski, and Sebastian A. Stoian. "Valence tautomerism in a cobalt-verdazyl coordination compound" Chemical Communications (2020): 4400-4403. https://doi.org/10.1039/d0cc01770a
COinS
