Effect of Surface Finishes on the Microstructure and Shear-Speed-Dependent Mechanical Properties of Sn-Ag-Cu-Based Solder Joints

Publication Date

10-27-2025

Document Type

Article

Publication Title

Journal of Electronic Materials

DOI

10.1007/s11664-025-12484-4

Abstract

This study systematically investigates the effects of surface finishes on the interfacial microstructure and shear-speed-dependent mechanical properties of Sn-Ag-Cu (SAC)-based solder joints. Two lead-free alloys, SAC305 and Innolot, were paired with four surface finishes, organic solderability preservative (OSP), immersion tin (ImSn), immersion silver (ImAg), and electroless nickel/immersion gold (ENIG), to assess their influence on intermetallic compound (IMC) formation, shear strength, and fracture behavior. Distinct IMC growth kinetics and morphologies were observed: OSP promoted rapid IMC growth with scalloped structures, while ENIG produced thinner, planar IMCs due to diffusion suppression. Innolot’s multi-element composition further refined IMC grains compared to SAC305. Shear testing across five speeds (0.01–1000 mm/s) revealed strong dependencies on both surface finish and strain rate. SAC305 joints followed a shear strength trend of ENIG > OSP > ImAg > ImSn, whereas Innolot exhibited more complex behavior, with OSP performing best at low speeds and ENIG at high speeds. Both alloys showed strain-rate strengthening, with SAC305 being more sensitive. Fracture modes shifted from ductile (bulk solder) to brittle (IMC interface) with increasing shear speed, with Innolot transitioning earlier. ENIG consistently outperformed other finishes by combining thin IMCs and robust adhesion, making it highly suitable for harsh environments. These findings offer valuable guidance for optimizing surface finishes in high-reliability electronic packaging.

Funding Number

202301BC070001-015

Keywords

fracture mechanism, IMC microstructure, shear properties, Sn-Ag-Cu based solder joints, strain rate effect, surface finishes

Department

Aviation and Technology

Share

COinS